The Poincaré Conjecture is about the shape of three-dimensional space. It was solved by the Russian mathematician Grigori Perelman, who posted the proof online, in three texts, without submitting it to any journal. It took a few years for the community to confirm that it was correct.
Perelman turned down the million dollars. Before that, he had already declined the Fields Medal and, in 1996, the prize of the European Mathematical Society. He said that the contribution of Richard Hamilton, who created the tools used in the proof, was no smaller than his own, and that taking the glory alone seemed unfair.
🔗 Official source: Clay Mathematics Institute